Creativity in Organic Synthesis by Jasjit S. Bindra PDF

By Jasjit S. Bindra

ISBN-10: 012099450X

ISBN-13: 9780120994502

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J. C. Farlie, G. L. Hodgson and T. Money, Chem. , 1196 (1969); J. Chem. Soc. Perkin 1,2109(1973). 2. G. L. Hodgson, D. F. MacSweeney and T. Money, Chem. , 766 (1971). 3. This useful procedure for converting alcohols to halides was developed by J. Hooz and S. S. H. Gilani, Canad. J. , 46, 86 (1968). (CH 2 OH) 2 , H + 2. MeS =C H 2 2. (CH 3 ) 2 CO L3. H 3 0 + -£? Campherenone 4. A mixture of bicyclic ketones, epimeric at C-7, was obtained in this reaction and carried through to the final stage of the synthesis.

Soc, 89, 6741 (1967). 14. E. Winterfeldt, T. Korth, D. Pike and M. Boch, Angew. Chem. Int. , 1 1 , 289 (1972). 15. E. Winterfeldt and H. Randuz, Chem. , 374 (1971); J. Warneke and E. Winterfeldt, Chem. , 105, 2120 (1972). V . ^ N Nc>0 H ■ t TI :02Me B u O2^ o C > / X ^ r rC0 k _2t*Bu ® ■Tsoci2, tßuOjC^^ t Bu DMFJ- 80% C0 2 Me (D 16. E. , 745, 23 (1971). 56 — | 0 2 , ΚΟ*Βιι 1 . H F o J-* 75 /o CREATIVITY IN ORGANIC SYNTHESIS C02Me —[ H 2- Pd-BaSO C0 2 Me 80% tßuC^C tßuC^C' CO^Bu C02lBu r('Bu)2AIH j l O r co^Bu Bu02C NaH, DMF L—-Etl ■To2, cuci2, DMFT i J Camptothecin 17.

15. E. Winterfeldt and H. Randuz, Chem. , 374 (1971); J. Warneke and E. Winterfeldt, Chem. , 105, 2120 (1972). V . ^ N Nc>0 H ■ t TI :02Me B u O2^ o C > / X ^ r rC0 k _2t*Bu ® ■Tsoci2, tßuOjC^^ t Bu DMFJ- 80% C0 2 Me (D 16. E. , 745, 23 (1971). 56 — | 0 2 , ΚΟ*Βιι 1 . H F o J-* 75 /o CREATIVITY IN ORGANIC SYNTHESIS C02Me —[ H 2- Pd-BaSO C0 2 Me 80% tßuC^C tßuC^C' CO^Bu C02lBu r('Bu)2AIH j l O r co^Bu Bu02C NaH, DMF L—-Etl ■To2, cuci2, DMFT i J Camptothecin 17. Several other excellent syntheses of camptothecin have been reported recently: A.

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Creativity in Organic Synthesis by Jasjit S. Bindra


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