Chromium Oxidations in Organic Chemistry - download pdf or read online

By Professor Gianfranco Cainelli, Professor Giuliana Cardillo (auth.)

ISBN-10: 3642693628

ISBN-13: 9783642693625

ISBN-10: 3642693644

ISBN-13: 9783642693649

Chromium oxidation, popular and extensively explored in natural chemistry because the very starting of this technological know-how, is a subject of present curiosity for the natural chemist as evidenced by way of the continual improvement of recent techni­ ques and approaches pronounced within the literature. Chromium oxidation is an easy technique which might be simply played within the laboratory and scaled up in besides. even supposing nearly each oxidizable natural useful team might endure chromium oxidation, crucial fields of appli­ cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of a few organometallic compounds. A excessive measure of selectivity is frequently attainable through determining the main appropriate reagent between these a number of ones now on hand. This ebook takes account of a few of the useful teams that suffer oxidation and the whole literature as much as 1982. it's been written within the desire to assist the substitute natural chemist in his experimental paintings. For this objective a few tables comprising yields and references were integrated; exact descriptions of general strategies are supposed to convey the experimental stipulations and the scope of the reactions. we want to thank Dr. Mario Orena for his beneficial clinical and technical assistence and Prof. Bruno Camerino, who learn the full manuscript and corrected the various blunders. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo desk of Contents I. creation . . . . . . . . . . .

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G. , Jacobs, H. J. : Tetrahedron Lett. 1969, 1157 14. : Coll. Czech. Ghem. Comm. 26, 2355 (1961) 15. : ibid. 24, 2741 (1959) 16. : Chern. Ber. 75,668 (1942) 17. : ibid. 90, 1987 (1957) 18. : ibid. 77, 191 (1944) 19. : ibid. 89, 1037 (1956) 20. Eck, e. , Hunter, D. : J. Chern. Soc. Chern. Comm. 1974, 865 21. Winnik, M. , Saunders, D. : ibid. 1976, 156 22. , Fessenden, J. , Agre, e. : Tetrahedron 7, 289 (1959) 23. : Bull. Soc. Chim. Fr. 1973, 707 24. Cfr. : Steroids, p. 507, New York, Reinhold Publ Corp.

Soc. 59, 662 (1937) 62. McNiven, N. : ibid. 76, 1725 (1954) 63. : J. Org. Chem. 40,1178 (1975) 64. Granchelli, F. , Neumeyer, J. : Tetrahedron 30, 3701 (1974) 65. , Fishel, D. : J. Org. Chem. 30, 1453 (1965) 66. : Org. Synth. 43, 80 (1963) 67. Fieser, L. , Campbell, W. , Fry, E. , M. : ibid. 61, 3216 (1939) G8. (a) Reitsema, R. , Allphin, N. : J. Org. Chem. 27, 27 (1962) (b) Lee, D. , Spitzer, U. : ibid. 34, 1493 (1969) 69. : Can. J. Chem. 36, 667 (1958) 70. Wiberg, K. : Tetrahedron Lett. , Balaban, A.

89, 1037 (1956) 20. Eck, e. , Hunter, D. : J. Chern. Soc. Chern. Comm. 1974, 865 21. Winnik, M. , Saunders, D. : ibid. 1976, 156 22. , Fessenden, J. , Agre, e. : Tetrahedron 7, 289 (1959) 23. : Bull. Soc. Chim. Fr. 1973, 707 24. Cfr. : Steroids, p. 507, New York, Reinhold Publ Corp. 1959 25. FIAT, Final Report nO 996 26. : Chern. Ber. 66, 1274 (1966) 27. : Mikrochemie ver. Mikrochem. Acta 33,51 (1978) 28. : Comprehensive Analytical Chemistry, Vol. 1B (ed. Wilson and Wilson), Amsterdam, Elsevier 1960 29.

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Chromium Oxidations in Organic Chemistry by Professor Gianfranco Cainelli, Professor Giuliana Cardillo (auth.)


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