Download PDF by Stanley M. Roberts, John Whittall: Catalysts for Fine Chemical Synthesis, Volume 5: Regio- and

By Stanley M. Roberts, John Whittall

ISBN-10: 0470090227

ISBN-13: 9780470090220

ISBN-10: 0470090235

ISBN-13: 9780470090237

Quantity five within the Catalysts for tremendous Chemical Synthesis sequence describes new techniques for the regio- and stereo-controlled alterations of compounds concerning oxidation or relief reactions. It describes a variety of catalysts, together with organometallic platforms, biocatalysts and biomimetics. This quantity additionally contains descriptions of a number of conversions, together with: Baeyer-Villiger oxidations; Epoxidation reactions; Hydroxylation reactions; Oxidation of alcohols to aldehydes, ketones and carboxylic acids; aid of ketones; and relief of alkenes together with α, β-unsaturated carbonyl compounds. The publication might be a big textual content for training artificial natural chemists in and academia.Protocols are written in a customary structure through the authors who've chanced on themHints, information and protection suggestion (where acceptable) is given to make sure that the methods are reproducibleIndications are given as to the diversity of beginning fabrics used and, the place acceptable, comparisons to substitute methodologyIncludes proper references to the first literature.

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REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . 2 SYNTHESIS AND APPLICATION OF PHOSPHINITE OXAZOLINE IRIDIUM COMPLEXES FOR THE ASYMMETRIC HYDROGENATION OF ALKENES . . . . . . . 1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4, 5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol . . . . . . . . 2 Synthesis of (4S,5S)-O-[1-Benzyl-1(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]diphenylphosphinite .

Org. Chem. 2005, 70, 5436–5441. 13. , Moge, M. and Sivadasan, S. Claisen Condensation as a Facile Route to an a-Alkoxy-cinnamate: Synthesis of Ethyl (2S)-2-Ethoxy-3-(4-hydroxyphenyl)propanoate. Org. Process Res. Dev. 2004, 8, 838–845. 14. Y. and Haurez, M. Synthesis of PPAR Agonist via Asymmetric Hydrogenation of a Cinnamic Acid derivative and Stereospecific Displacement of (S)-2-Chloropropionic Acid. Org. Lett. 2005, 7, 1947–1950. 30 REGIO- AND S TEREO-CONTRO LLED OXIDATIONS AND RE DUCTIONS 15.

2006, WO 2006016116 A1. 45. Brown, H. C. and Ramachandran, P. V. Asymmetric Reduction with Chiral Organoboranes Based on a-Pinene. Acc. Chem. Res. 1992, 25, 16–24. 46. Schwink, L. and Knochel, P. Enantioselective Preparation of C2-Symmetrical Ferrocenyl Ligands for Asymmetric Catalysis. Chem. Eur. J. 1998, 4, 950–968. 47. -E. and Rosling, A. Highly Catalytic Enantioselective Reduction of Aromatic Ketones using Chiral Polymer-supported Corey, Bakshi, and Shibata Catalysts. Tetrahedron Asymmetry 2004, 15, 1495–1499.

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Catalysts for Fine Chemical Synthesis, Volume 5: Regio- and Stereo-Controlled Oxidations and Reductions'', Publisher: by Stanley M. Roberts, John Whittall


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