By Wolfgang Weigand, Philippe Schollhammer
This publication offers an outline of bioinspired metal-sulfur catalysis by means of protecting buildings, actions and version complexes of enzymes displaying steel sulphur moieties of their energetic middle.
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Additional info for Bioinspired Catalysis: Metal-Sulfur Complexes
Consequently, it is not easy to understand how complex proteins became associated with these metal active sites. There are two possibilities: either the metal cluster was originally captured from the inorganic environment by simple peptides being later synthesized by increasingly complex enzymes during an evolutive process, or we are dealing with a case of a chemical constraint where metal-sulﬁde species are the best suited to catalyze gas-based reactions both inorganically and biologically. By far, the most abundant and plastic metal-containing clusters are of the Fe–S type.
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Bioinspired Catalysis: Metal-Sulfur Complexes by Wolfgang Weigand, Philippe Schollhammer