Download PDF by Wolfgang Weigand, Philippe Schollhammer: Bioinspired Catalysis: Metal-Sulfur Complexes

By Wolfgang Weigand, Philippe Schollhammer

ISBN-10: 3527333088

ISBN-13: 9783527333080

This publication offers an outline of bioinspired metal-sulfur catalysis by means of protecting buildings, actions and version complexes of enzymes displaying steel sulphur moieties of their energetic middle.

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Consequently, it is not easy to understand how complex proteins became associated with these metal active sites. There are two possibilities: either the metal cluster was originally captured from the inorganic environment by simple peptides being later synthesized by increasingly complex enzymes during an evolutive process, or we are dealing with a case of a chemical constraint where metal-sulfide species are the best suited to catalyze gas-based reactions both inorganically and biologically. By far, the most abundant and plastic metal-containing clusters are of the Fe–S type.

Astrobiology, 10, 973–988. P. and Fritz, M. (1993) Emergence of CNH and cyano complex based organometallic chemistry. Chem. , 93, 1243–1280. Huber, C. and Wächtershäuser, G. (1998) Peptides by activation of amino acids on (Fe,Ni)S surfaces: implications for the origin of life. Science, 281, 670–672. , and Wächtershäuser, G. (2003) A possible primordial peptide cycle. Science, 301, 938–940. M. (2009) The Hadean crust: evidence from >4 Ga zircons. Annu. Rev. Earth Planet. , 37, 479–505. S. (2006) The origin and emergence of life under impact bombardment.

B, 361, 1787–1808. Wächtershäuser G. 2010. ) L. L. Barton, M. Mandl, A. Loy Geomicrobiology: Molecular and Environmental Perspective. Springer, Dordrecht, pp. 1-35. A. , and Wolfenden, R. (2010) Impact of temperature on the time required for the establishment of primordial biochemistry, and for the evolution of enzymes. Proc. Natl. Acad. Sci. , 107, 22102–22105. , and McCollom, T. (2006) Investigation of single carbon compounds under hydrothermal conditions. Geochim. Cosmochim. Acta, 70, 446–460.

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Bioinspired Catalysis: Metal-Sulfur Complexes by Wolfgang Weigand, Philippe Schollhammer


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