By L. Ƶechmeister (auth.)
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No t r a n s i e n t s could be detected i n the nanosecond time s c a l e , suggesting that the ground s t a t e enol [S^ ( l b ) i n scheme 1] has a l i f e t i m e l e s s than 1 x 10~9 sec. These r e s u l t s s t r o n g l y imply that processes (3) and (4) are r e s p o n s i b l e f o r the d e a c t i v a t i o n of s i n g l e t energy i n these systems. A s m a l l , non zero t r i p l e t y i e l d i s p o s t u l a t e d i n the copolymer both to account f o r the photodegradation data and the t r a n s i e n t s p e c t r a l d a t a .
Encinas J. Am. Chem. , 1979, 101, 6965. 12. ; J . Am. Chem. , 1979, 101, 2146. RECEIVED October 15, 1980. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1981. 3 Mechanisms of Photodegradation of Ultraviolet Stabilizers and Stabilized Polymers AMITAVA GUPTA—Energy & Materials Research Section, Jet Propulsion Laboratory, California Institute of Technology, Pasadena CA 91103 GARY W. SCOTT—Department of Chemistry, University of California—Riverside, Riverside, CA 92521 DAVID KLIGER—Division of Natural Sciences, University of California—Santa Cruz, Santa Cruz, CA 98064 Transparent, durabl ultraviolet (300-380 nm screening agents in a photo-stable acrylic such as PMMA (1,2).
Macromolecules, 13 (4) 821 (1980). 10. , and Moacanin, J . ; Macromolecules, In press. 11. Anderson, R. , Damaschen, D. E. Scott, G. , and Talley, L. ; J. Chem. , 71, 1134 (1978). 12. ; Unpublished Results. 13. , and Kramer, H. E. ; Europ. Polym. J . , 13, 501 (1977). 14. Kramer, H. E. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1981. 42 PHOTODEGRADATION AND PHOTOSTABILIZATION OF COATINGS Films and Coatings Symposium, ACS National Meeting, Houston, March 1980. 15. , Macromolecules, 1978, 11, 312.
Bibliography of Papers: 1913–1958 by L. Ƶechmeister (auth.)