By Tristram Chivers
Chalcogen-nitrogen chemistry comprises the examine of compounds that express a linkage among nitrogen and sulfur, selenium or tellurium atoms. Such stories have either primary and sensible significance. A advisor to Chalcogen-Nitrogen Chemistry examines the function of chalcogen-nitrogen compounds in components starting from solid-state inorganic chemistry to biochemistry. The dialogue covers primary questions about the bonding in electron-rich structures, in addition to strength functional functions of polymers and fabrics with novel magnetic or electric houses. This e-book is the one account of this crucial subject to seem within the final twenty-five years, and matched with its broad literature insurance of very contemporary advancements, this accomplished consultant is vital for someone operating within the box. The therapy is exclusive in supplying a comparability of sulfur, selenium and tellurium platforms, with an process meant to stress normal innovations that might be beneficial to the non-specialist. each one bankruptcy is designed to be self-contained, and there are vast cross-references among chapters.
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Additional info for A Guide To Chalcogen-Nitrogen Chemistry
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6), is formed as an intermediate in the synthesis of S4N4. 2 From Amines and Amido–Lithium or Sodium Reagents The reactions of amines or amido-lithium compounds with chalcogen halides provide a convenient source of a variety of important chalcogennitrogen reagents. The reactions of LiN(SiMe3)2 with SCl2, Se2Cl2 or TeCl4 in hexane or diethyl ether produce the chalcogen(II) diamides E[N(SiMe3)2]2 (E = S, Se, Te)11, 12 in good yields (Eq. 3). 3) The reactivity of the Si–N bonds in these reagents can be utilized in further synthesis of chalcogen-nitrogen compounds.
Dorn and I. Manners, New Inorganic Polymers Containing Phosphorus, in J-P. ) New Aspects in Phosphorus Chemistry III: Topics Curr. , 229, 141-167 (2002). (h) Selenium– and Tellurium–Nitrogen Compounds M. Björgvinsson and H. W. Roesky, The Structures of Compounds Containing Se–N and Te–N Bonds, Polyhedron, 10, 2353 (1991). T. M. Klapötke, Binary Selenium–Nitrogen Species and Related Compounds, in R. ) The Chemistry of Inorganic Ring Systems, Elsevier, pp. 409-427 (1992). T. D. Doxsee, Heterocyclic Selenium– and Tellurium–Nitrogen Compounds, Comments Inorg.
A Guide To Chalcogen-Nitrogen Chemistry by Tristram Chivers